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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 8(69), p. m446-m447, 2013

DOI: 10.1107/s1600536813017376

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Dichloridobis[3-(4-chlorophenyl)-2,N,N-trimethyl-2,3-dihydro-1,2,4-oxadiazole-5-amine-κN4]platinum(II)–4-chlorobenzaldehyde (1/1)

Journal article published in 2013 by Andreii S. Kritchenkov, Vladislav V. Gurzhiy, Nadezhda A. Bokach ORCID, Valentina A. Kalibabchuk
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title 1:1 co-crystal, [PtCl2(C11H14ClN3O)2]·C7H5ClO, the coordination polyhedron of the PtII atom is slightly distorted square-planar with the chloride and 2,3-di­hydro-1,2,4-oxa­diazole ligands mutually trans, as the Pt atom lies on an inversion center. The 4-chloro­benzaldehyde mol­ecules are statistically disordered about an inversion centre with equal occupancies for the two positions. The PtII complex forms a three-dimensional structure through C—H⋯Cl and weaker C—H⋯O inter­actions with the 4-chloro­benzaldehyde mol­ecule.