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CSIRO Publishing, Australian Journal of Chemistry, 7(41), p. 1117

DOI: 10.1071/ch9881117

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Investigation of a New Xanthate Ligand. The Crystal and Molecular Structures of Nickel and Cadmium (Methoxyethyl)xanthates

Journal article published in 1988 by Bf Abrahams ORCID, Bf Hoskins, Ert Tiekink, G. Winter
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The crystal structures of Ni(S2COCH2CH2OCH3)2 and Cd (S2COCH2CH2OCH3)2 have been determined. Crystals Ni(S2COCH2CH2OCH3)2 are orthorhombic, Pbca , with a 7.852(1), b 7.126(2), c 24.963(4)Ǻ, Z 4. Crystals of Cd (S2COCH2CH2OCH3)2 are monoclinic, P21/c, with a 12.712(2), b 4.215(1), c 13.400(2)Ǻ, β 104.60(1)°, Z 2. In both structures the central metal atom is coordinated by the sulfur atoms in a planar arrangement, an unexpected observation for the cadmium compound.