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CSIRO Publishing, Australian Journal of Chemistry, 5(63), p. 845

DOI: 10.1071/ch10014

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Speciation of Chlorometallate Ionic Liquids Based on Gallium(III) and Indium(III)

Journal article published in 2010 by Christopher Hardacre, Richard W. Murphy, Kenneth R. Seddon, Geetha Srinivasan, Mazgorzata Swadźba-Kwa(ś)ny ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A range of ionic liquids was prepared by mixing 1-alkyl-3-methylimidazolium chloride with gallium(iii) chloride or indium(iii) chloride in various ratios, producing both acidic and basic compositions. Their speciation was investigated using 71Ga NMR or 115In NMR spectroscopy, as well as extended X-ray absorption fine structure. Polynuclear Lewis acidic anions, [MxCl3x+1]–, were found in chlorogallate(iii) ionic liquids, but not in chloroindate(iii) systems.