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American Institute of Physics, Applied Physics Letters, 17(106), p. 173502, 2015

DOI: 10.1063/1.4919109

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Non-ferroelectric nature of the conductance hysteresis in CH3NH3PbI3 perovskite-based photovoltaic devices

This paper is available in a repository.
This paper is available in a repository.

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Abstract

We present measurements of conductance hysteresis on CH3NH3PbI3 perovskite thin films, performed using the double-wave method, in order to investigate the possibility of a ferroelectric response. A strong frequency dependence of the hysteresis is observed in the range of 0.1 Hz to 150 Hz, with a hysteretic charge density in excess of 1000 {μ}C/cm2 at frequencies below 0.4 Hz - a behaviour uncharacteristic of a ferroelectric response. We show that the observed hysteretic conductance, as well as the presence of a double arc in the impedance spectroscopy, can be fully explained by the migration of mobile ions under bias on a timescale of seconds. Our measurements place an upper limit of approximately 1 {μ}C/cm2 on any intrinsic frequency-independent polarisation, ruling out ferroelectricity as the main cause of current-voltage hysteresis and providing further evidence of the importance of ionic migration in modifying the efficiency of CH3NH3PbI3 devices.