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Published in

International Union of Crystallography, Acta Crystallographica Section C: Crystal Structure Communications, 11(59), p. m432-m434, 2003

DOI: 10.1107/s0108270103020225

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Hexafluorophosphates of chlorotris(dimethyl sulfide)platinum(II) and bromotris(dimethyl sulfide)platinum(II)

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The title compounds, chlorotris(dimethyl sulfide-κS)platinum(II) hexafluorophosphate, [PtCl(C2H6S)3]PF6, and bromotris(dimethyl sulfide-κS)platinum(II) hexafluorophosphate, [PtBr(C2H6S)3]PF6, are isomorphous and are composed of [PtX(dms)3]+ complex cations (X = Cl and Br, and dms is dimethyl sulfide) and PF6 anions. The Pt atom is coordinated by three S atoms and one X atom in a pseudo-square-planar coordination, with Pt—S distances in the range 2.293 (1)–2.319 (2) Å. Two dms ligands have a staggered conformation with respect to the coordination plane, while the third is rotated by ∼90° compared with the orientation of the other two. The packing can be described as consisting of [PtX(dms)3]2(PF6)2 units with a centre of symmetry. In this description, the PtII atom has a pseudo-octahedral coordination, with four normal bonds and two long weak interactions. Density-functional theory calculations show that a conformation in which one dms ligand is not staggered is less favourable than having all three dms ligands staggered.