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American Chemical Society, Organic Letters, 26(4), p. 4635-4637, 2002

DOI: 10.1021/ol0270069

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Efficient Sensitized Photooxygenation in Water by a Porphyrin−Cyclodextrin Supramolecular Complex

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The 2:1 inclusion complex between (2,3,6-tri-O-methyl)-β-cyclodextrin (TMβCD) and 5,10,15,20-tetrakis(4-sulfonatophenyl)-porphyrin (TPPS4) behaves as a supramolecular sensitizer in water providing photooxygenation with turnover numbers up to 30 000 with a very minor sensitizer bleaching (