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American Chemical Society, Journal of Physical Chemistry C, 2(111), p. 830-839, 2006

DOI: 10.1021/jp064565e

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Higher Catalytic Activity of $Nano-Ce_{1-x-y}Ti_xPd_yO_{2-δ}$ Compared to $Nano-Ce_{1-x}Pd_xO_{2-δ}$ for CO Oxidation and $N_2O$ and NO Reduction by CO: Role of Oxide Ion Vacancy

Journal article published in 2006 by Tinku Baidya ORCID, A. Marimuthu, M. S. Hegde, N. Ravishankar, Giridhar Madras
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Nano-$Ce_{0.73}Ti_{0.25}Pd_{0.02}O_{2-δ}$ solid solution, prepared by solution combustion method, has been synthesized. The catalyst has been characterized by XRD, HRTEM and XPS. Synergistic interaction of Pd with Ti/Ce is very strong because of ionic substitution. The reducibility of $Ce_{0.73}Ti_{0.25}Pd_{0.02}O_{2-δ}$ is about 5 times higher compared to that of $Ce_{0.98}Pd_{0.02}O_{2-δ}$ below 140 °C. The easy removal of oxygen from the more reducible Ti containing support plays a major role in showing higher catalytic activity of this material for CO oxidation and $N_2O$ and NO reduction by CO. The catalyst shows 100% $N_2$ selectivity above 240 °C and high reaction rates compared to other catalysts reported in the literature. It has been shown that oxide ion vacancy creation in the support promotes the adsorption and dissociation of NO or $N_2O$ at a lower temperature. Kinetic models based on a bifunctional mechanism were used to determine the reaction rate coefficients.