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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 7(66), p. m862-m863, 2010

DOI: 10.1107/s1600536810023950

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Tripyridiniumcis-tetrachloridodioxidomolybdate(VI) chloride

Journal article published in 2010 by José A. Fernandes, Ana C. Gomes ORCID, Sónia Figueiredo, Sandra Gago ORCID, Paulo J. A. Ribeiro-Claro, Isabel S. Gonçalves ORCID, Filipe A. Almeida Paz
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H⋯Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octa-hedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.