Vanadium-Bromoperoxidase-Mimicking Systems: Direct Evidence of a Hypobromite-Like Vanadium Intermediate
This paper was not found in any repository, but could be made available legally by the author.
Full text: Unavailable
Published version:
archiving forbidden
Data provided by 
Abstract
we report a direct observation, by electrospray ionization mass spectrometry, of the intermediate [VO(OH2)(OH)- (OBr)]+, which may be involved in the catalytic cycle of the V-HalPO enzymes. Ab initio calculations also support the stability of such a species.