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Wiley, Angewandte Chemie, 29(127), p. 8531-8534, 2015

DOI: 10.1002/ange.201500994

Wiley, Angewandte Chemie International Edition, 29(54), p. 8411-8414

DOI: 10.1002/anie.201500994

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Halogen-Bond-Assisted Guest Inclusion in a Synthetic Cavity

Journal article published in 2015 by Hiroki Takezawa, Takashi Murase, Giuseppe Resnati ORCID, Pierangelo Metrangolo, Makoto Fujita
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The confined space inside a self-assembled cage enhanced halogen bonding (XB) between iodoperfluorocarbons (XB donors) and NO3- anions or H2O molecules (XB acceptors), as confirmed by NMR spectroscopy in solution and by X-ray crystallography in the solid state. The cavity also bound an XB donor-acceptor pair, C6F3I3 and C6H5NMe2, in a selective pairwise fashion.