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SAGE Publications, Applied Spectroscopy, 1(43), p. 118-122

DOI: 10.1366/0003702894201987

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Infrared and Raman Spectra of Phthalimide-<sup>15</sup>N-H and Phthalimide-<sup>15</sup>N-D

Journal article published in 1989 by J. F. Arenas, J. I. Marcos, F. J. Ramírez ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A study of the infrared and Raman spectra of previously synthesized phthalimide-15N-H and phthalimide-15N-D has been carried out. With the new data obtained, the vibrational spectra of the phthalimide molecule in a C2 v* symmetry has been reassigned, but taking into account that the molecule in the solid state forms dimers bonded by intermolecular hydrogen bonds; these dimers have a Ci symmetry. On the other hand, a semi-empiric calculation of the force fields of this molecule has been carried out by the MINDO/3-FORCE method, which required a prior optimization of the molecular geometry; the force field was transformed to the space of internal coordinates.