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Wiley, Angewandte Chemie, 22(113), p. 4359-4362, 2001

DOI: 10.1002/1521-3757(20011119)113:22<4359::aid-ange4359>3.0.co;2-e

Wiley, Angewandte Chemie International Edition, 22(40), p. 4229-4232

DOI: 10.1002/1521-3773(20011119)40:22<4229::aid-anie4229>3.3.co;2-7

Wiley, Angewandte Chemie International Edition, 22(40), p. 4229-4232, 2001

DOI: 10.1002/1521-3773(20011119)40:22<4229::aid-anie4229>3.0.co;2-g

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1,2-Bis(3-methyl-imidazolin-2-ylium iodobromoselenanide)ethane: Oxidative Addition of IBr at the Se Atom of a &gt;C=Se Group

Journal article published in 2001 by M. Carla Aragoni, Massimiliano Arca, Alexander J. Blake ORCID, Francesco A. Devillanova, Wolf-Walther du Mont, Alessandra Garau, Francesco Isaia, Vito Lippolis, Gaetano Verani, Claire Wilson ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Almost linear I-Se-Br groups with d(Se−Br)>d(Se−I) occur in 1⋅2 IBr (see structure), the first “T-shaped” Se adduct with IBr, which was synthesized by the oxidative addition of IBr to 1,2-bis(3-methylimidazoline-2-selonyl)ethane (1) in MeCN. Density functional theory calculations indicate the intramolecular Br⋅⋅⋅H interactions as being responsible for the peculiar structural features of the I-Se-Br groups.