A systematic study of electron or hole transfer along DNA dimers, trimers and polymers is presented with a tight-binding approach at the base-pair level, using the relevant on-site energies of the base-pairs and the hopping parameters between successive base-pairs. A system of $N$ coupled differential equations is solved numerically with the eigenvalue method, allowing the temporal and spatial evolution of electrons or holes along a $N$ base-pair DNA segment to be determined. Useful physical quantities are defined and calculated including the maximum transfer percentage $p$ and the pure maximum transfer rate $\frac{p}{T}$ for cases where a period $T$ can be defined, as well as the pure mean carrier transfer rate $k$ and the speed of charge transfer $u=kd$, where $d = N \times$ 3.4 {Å} is the charge transfer distance. The inverse decay length $β$ used for the exponential fit $k = k_0 \exp(-β d)$ and the exponent $η$ used for the power law fit $k = k_0' N^{-η}$ are computed. The electron and hole transfer along polymers including poly(dG)-poly(dC), poly(dA)-poly(dT), GCGCGC., ATATAT. is studied, too. $β$ falls in the range $≈$ 0.2-2 {Å}$^{-1}$, $k_0$ is usually 10$^{-2}$-10$^{-1}$ PHz although, generally, it falls in the wider range 10$^{-4}$-10 PHz. $η$ falls in the range $≈$ 1.7-17, $k_0'$ is usually $≈ 10^{-2}$-10$^{-1}$ PHz, although generally, it falls in the wider range $≈10^{-4}$-10$^3$ PHz. Finally, the results are compared with the predictions of Wang et al. Phys. Rev. Lett. 93, (2004) 016401, as well as experiments, including Murphy et al. Science 262, 1025 (1993); Arkin et al. Science 273, 475 (1996); Giese et al. Angew. Chem. Int. Ed. 38, 996 (1999); Giese et al. Nature 412, 318 (2001). This method allows to assess the extent at which a specific DNA segment can serve as an efficient medium for charge transfer. ; Comment: 16 pages, 7 figures, 4 tables. arXiv admin note: text overlap with arXiv:1312.6842