Structural investigation of the hydroxy-propynal molecular ion
Journal article published in 1993 by
L. Pandolfo 
,
G. Paiaro,
Á. Somogyi,
A. Somogyi,
S. Catinella,
P. Traldi
,
G. Paiaro,
Á. Somogyi,
A. Somogyi,
S. Catinella,
P. Traldi
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Abstract
A formyl ketenyl platinum derivative, trans-μ1-(PCy3)2(H)Pt[C(CHO)CO] (where Cy represents a cyclohexyl group), when reacted with HCl, gives a C3H2O2 species among the reaction products. The structure was investigated mass spectrometrically by study of the reactions of metastable ions, and the information gained was combined with data from theoretical calculations to rationalize the structure of the C3H2O2 molecule.