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Elsevier, Ceramics International, 8(41), p. 9314-9320, 2015

DOI: 10.1016/j.ceramint.2015.03.271

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Electrochemically synthesized mesoporous thin films of ZnO for highly efficient dye sensitized solar cells

Journal article published in 2015 by F. Anderson S. Lima ORCID, Igor F. Vasconcelos, Monica Lira-Cantu ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

In this work, nanostructured thin films of ZnO were electrochemically grown on FTO substrates. The morphology was tuned by modifying the synthesis parameters. The synthesis was carried out by applying Zn(NO3)·6H2O as the sole component of the aqueous electrolyte, avoiding the use of capping agents. The composition and morphology of the prepared ZnO were characterized by energy-dispersive X-ray spectroscopy (EDX) and scanning electron microscopy (SEM), respectively. The as-deposited films were applied as electrodes in dye sensitized solar cells (DSCs). The performance of the cells was investigated by J×V curves and IPCE (incident photon to charge carrier efficiency) measurements. The SEM analysis demonstrated a direct relationship between ZnO morphology and Zn precursor concentration. It has been shown that the lower the concentration is, the more porous the morphology is. Increasing the amount of dye adsorbed on the ZnO decreased the power conversion efficiency of the final DSCs. The best cell presented the following parameters: open circuit voltage VOC=0.59V, short circuit current JSC=7.64mA/cm2, fill factor FF=50.41%, and power conversion efficiency PCE=2.27%. ; The authors are grateful to the Brazilian research agencies Conselho Nacional de Desenvolvimento Científico e Tecnológico - CNPq for the fellowship (246430/2012-5). The authors are also grateful to Fundação Cearense de Apoio ao Desenvolvimento Científico e Tecnológico (FUNCAP) and Secretaria da Educação do Ceará (SEDUC-CE) for financial support. ; Peer Reviewed