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Wiley, Angewandte Chemie, 40(125), p. 10694-10698, 2013

DOI: 10.1002/ange.201304887

Wiley, Angewandte Chemie International Edition, 40(52), p. 10500-10504, 2013

DOI: 10.1002/anie.201304887

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{Mo24Fe12} Macrocycles: Anion Templation with Large Polyoxometalate Guests

Journal article published in 2013 by Xikui Fang, Laura Hansen, Fadi Haso, Panchao Yin ORCID, Abhishek Pandey, Larry Engelhardt, Igor I. Slowing, Tao Li, Tianbo Liu, Marshall Luban, David C. Johnston
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-templated supramolecular chemistry. The Keggin (left) and Dawson-type (right) polyoxoanions direct the assembly of giant metallomacrocycles through an array of weak hydrogen-bonding interactions. The concerted action of multiple hydrogen bonds keeps the templating guests embedded within the hosts, even in the solution state.