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American Chemical Society, Inorganic Chemistry, 14(45), p. 5239-5241, 2006

DOI: 10.1021/ic0602446

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O2Chemistry of Dicopper Complexes with Alkyltriamine Ligands. Comparing Synergistic Effects on O2Binding

Journal article published in 2006 by Anna Company, Diana Lamata, Albert Poater, Miquel Solà ORCID, Elena V. Rybak-Akimova, Lawrence Que, Xavier Fontrodona, Teodor Parella ORCID, Antoni Llobet, Miquel Costas ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constrains to the Cu ions have been synthetized, and their reactivity towards O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation.