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Single and double substrate insertion into the TiNαbonds of terminal titanium hydrazides

Journal article published in 2010 by Pei-Jen Tiong, A. Daniel Schofield, Jonathan D. Selby, Ainara Nova ORCID, Eric Clot, Philip Mountford
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

Nitriles, CO(2) and isocyanates undergo net single or double insertion reactions into the Ti=N(alpha) multiple bonds of terminal titanium hydrazides. These are the first such examples of this type of reactivity for any transition metal hydrazide complex.