Published in

American Institute of Physics, The Journal of Chemical Physics, 13(143), p. 134302

DOI: 10.1063/1.4931645

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Complete dissociation branching fractions and Coulomb explosion dynamics of SO2 induced by excitation of O 1s pre-edge resonances

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Data provided by SHERPA/RoMEO

Abstract

Fragmentation processes of SO2 following excitation of the six main O 1s pre-edge resonances, as well as above the ionization threshold and below the resonances, are studied using a position-sensitive time-of-flight ion imaging detector, and the associated dissociation branching ratios and break-up dynamics are determined. In order to distinguish between the O+ and S2+ fragments of equal mass-to-charge ratio, the measurements have been performed with the isotopically enriched S18O2 sample. By analysis of the complete set of the fragment momentum vectors, the β values for the fragments originating from the SO+ + O+ break-up and the kinetic energy release for fragmentation channels of both SO22+ and SO23+ parent ions are determined. We also present results on the three-body break-up dynamics.