Wiley, Angewandte Chemie International Edition, 1(48), p. 215-218, 2008
Wiley, Angewandte Chemie International Edition, 6(48), p. 1005-1005
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The most-oxidized iridium oxides known to date are prepared in a hydroxide flux under normal pressure. They contain iridium centers exclusively in the +VI oxidation state and are characterized crystallographically. The picture shows the structure of the Ln2K2IrO7 (Ln=Nd, Sm) and its structural components: IrO6 octahedra (black), KO10 polyhedra (beige), LnO10 polyhedra (blue).