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Wiley, Angewandte Chemie International Edition, 1(48), p. 215-218, 2008

DOI: 10.1002/anie.200804045

Wiley, Angewandte Chemie International Edition, 6(48), p. 1005-1005

DOI: 10.1002/anie.200990012

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Nd2K2IrO7and Sm2K2IrO7: Iridium(VI) Oxides Prepared under Ambient Pressure

Journal article published in 2008 by Samuel J. Mugavero, Mark D. Smith, Won-Sub Yoon, Hans-Conrad zur Loye ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The most-oxidized iridium oxides known to date are prepared in a hydroxide flux under normal pressure. They contain iridium centers exclusively in the +VI oxidation state and are characterized crystallographically. The picture shows the structure of the Ln2K2IrO7 (Ln=Nd, Sm) and its structural components: IrO6 octahedra (black), KO10 polyhedra (beige), LnO10 polyhedra (blue).