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American Chemical Society, Organometallics, 5(14), p. 2164-2166, 1995

DOI: 10.1021/om00005a014

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Synthesis and Characterization of a (Ketenyl)metal Cluster Complex, an Intermediate in the Oxidative Decarbonation of an Acetylide Ligand

Journal article published in 1995 by Te-Kun Huang, Yun Chi ORCID, Shie-Ming Peng, Gene-Hsiang Lee, Sue-Lein Wang, Fen-Ling Liao, Huang Tk;Chi Y;Peng Sm;Lee Gh;Wang Sl;Liao Fl
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

2010302010121 ; 化學系 ; Oxidation, of the acetylide cluster Cp(*)WOs(3)-(CO)(9)(C-2)(C(2)Ph) (2) in toluene produced the ketenyl complex Cp(*)WOs(3)(CO)(9)(C-2)(OC(2)Ph) (3). Compound 3 releases a CO group to afford the alkylidyne cluster Cp(*)WOs(3)(CO)(9)(C-2)(CPh) (4) upon heating, which provides an example of sequential conversion of acetylide to ketenyl and alkylidyne