American Association for the Advancement of Science, Science, 6158(342), p. 611-614, 2013
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Imaging Hydrogen Bonds The decoration of atomic force microscope tips with terminal CO molecules has afforded much higher resolution of the bonding of adsorbed molecules. Zhang et al. (p. 611 , published online 26 September) show that this method, in combination with density function theory calculations, can image and characterize hydrogen-bonding contacts formed between 8-hydroxyquinoline molecules adsorbed on the (111) surface of copper under cryogenic conditions. At room temperature, a different bonding configuration was revealed that was the result of the molecules dehydrogenating on the copper surface and coordinating with surface copper atoms.