Published in

American Association for the Advancement of Science, Science, 6158(342), p. 611-614, 2013

DOI: 10.1126/science.1242603

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Real-Space Identification of Intermolecular Bonding with Atomic Force Microscopy

Journal article published in 2013 by Jun Zhang, Pengcheng Chen ORCID, Bingkai Yuan, Wei Ji, Zhihai Cheng, Xiaohui Qiu
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Imaging Hydrogen Bonds The decoration of atomic force microscope tips with terminal CO molecules has afforded much higher resolution of the bonding of adsorbed molecules. Zhang et al. (p. 611 , published online 26 September) show that this method, in combination with density function theory calculations, can image and characterize hydrogen-bonding contacts formed between 8-hydroxyquinoline molecules adsorbed on the (111) surface of copper under cryogenic conditions. At room temperature, a different bonding configuration was revealed that was the result of the molecules dehydrogenating on the copper surface and coordinating with surface copper atoms.