Dissemin is shutting down on January 1st, 2025

Published in

Elsevier, Journal of Hazardous Materials, 1-3(190), p. 460-465

DOI: 10.1016/j.jhazmat.2011.03.085

Links

Tools

Export citation

Search in Google Scholar

Electrochemical oxidation of stabilized landfill leachate on DSA electrodes

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Red circle
Postprint: archiving forbidden
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

The electrochemical oxidation of stabilized landfill leachate with 2960 mg L(-1) chemical oxygen demand (COD) over a Ti/IrO(2)-RuO(2) anode was investigated in the presence of HClO(4) as the supporting electrolyte. Emphasis was given on the effect of electrolysis time (up to 240 min) and temperature (30, 60 and 80 degrees C), current density (8, 16 and 32 mA cm(-2)), initial effluent's pH (0.25, 3,5 and 6), HClO(4) concentration (0.25 and 1 M) and the addition of NaCl (20 and 100 mM) or Na(2)SO(4) (20 mM) as source of extra electrogenerated oxidants on performance; the latter was evaluated regarding COD, total carbon (TC), total phenols (TPh) and color removal. Moreover, the anode was studied by scanning electron microscopy and cyclic voltammetry. The main parameters affecting the process were the effluent's pH and the addition of salts. Treatment for 240 min at 32 mA cm(-2) current density, 80 degrees C and the pH adjusted from its inherent value of 0.25 (i.e. after the addition of HClO(4)) to 3 yielded 90% COD, 65% TC and complete color and TPh removal at an electricity consumption of 35 kWh kg(-1) COD removed. Comparable performance (i.e. 75% COD reduction) could be achieved without pH adjustment but with the addition of 100 mM NaCl consuming 20 kWh kg(-1) COD removed.