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American Chemical Society, Organometallics, 10(24), p. 2259-2261, 2005

DOI: 10.1021/om050172a

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Reversible Sm(III)/Sm(II) redox chemistry of an organosamarium(III) complex

Journal article published in 2005 by Jun Wang, Ruth I. J. Amos, Alistair S. P. Frey, Michael G. Gardiner ORCID, Marcus Lawford Cole, Peter C. Junk ORCID
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

A binuclear samarium(III) complex featuring the -1:1-bound dianion of 1,4-di-tert-butyl-1,4-diazabuta-1,3-diene has been prepared which exhibits reversible redox behavior, reverting to the samarium(II) precursor when dissolved in tetrahydrofuran. The new samarium(III) complex has been characterized by 1H and 13C NMR spectral data, microanalytical data, magnetic moment measurements in solution, and an X-ray crystal structure determination. ; Jun Wang, Ruth I. J. Amos, Alistair S. P. Frey, and Michael G. Gardiner, Marcus L. Cole and Peter C. Junk ; Copyright © 2005 American Chemical Society