The phenomenon of vortex merging in two-dimensional hydrodynamics has been investigated through direct numerical simulations. The fast and local processes that occur during the turbulent relaxation of a randomly initialized system in periodic geometry have been examined. The analysis reveals that many of the coherent structures can be described by a local principle of maximization of entropy. The validity of this entropy principle has been further confirmed by time-dependent statistics using a contour-tracking technique. Implications for the description of persistent coherent vortices commonly observed in nature are suggested, including growing evidence for the wide applicability of maximum entropy-based relaxation principles.