Nanocrystalline Pr0.65(Ca0.7Sr0.3)MnO3 show large magnetocaloric effect at their charge order transition temperature (TCO) as well as at the temperature at which the spontaneous destabilization of charge ordered state occurs (TM). In comparison to their polycrystalline bulk form, TM’s are substantially enhanced in the cases of nanocrystalline samples, whereas their TCO’s remain almost unchanged. Although there is no clear signature of charge order transition in the temperature dependence of magnetic susceptibility and resistivity for the sample with the lower particle size, a clear maxima due to charge order transition is visible in its temperature dependence of change in magnetic entropy.