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Published in

American Institute of Physics, The Journal of Chemical Physics, 15(128), p. 155105

DOI: 10.1063/1.2898091

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Diffusion-influenced reactions of particles with several active sites

Journal article published in 2008 by Konstantin L. Ivanov ORCID, Nikita N. Lukzen
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The main concern of the present work is consideration of sterically specific liquid-phase reactions in the case where one of the reactants has several active sites. In kinematic approximation we derived compact formulas for partial rate constants of individual active sites. Reaction rates are expressed via the kinetic rate constants and convolutions of the free Green functions over reaction zones. These results are valid for arbitrary geometry of reactants and active sites. Effects of mutual influence of the active sites were studied, their simple estimate was proposed.