La 2 ∕ 3 Ca 1 ∕ 3 Mn O 3 (LCMO)/YBa1.8Eu0.2Cu3O7 (YBECO) multilayers on yttrium-stabilized ZrO2 are fabricated. YBECO sublayer is well crystallized in c-axis orientation, while LCMO sublayer crystallized in (001) textured structure, which forms special mosaic structure. By magnetization measurements, we confirm that the cluster spin glass existed in LCMO/YBECO multilayers in low temperature, which may scatter the transport electrons. Superconductivity cannot be observed when thickness of YBECO layer is less than 24nm. The magnetoresistance ratio depends on the thickness of YBECO layer. The magnetotransport properties of the multilayers make it very promising to provide a technological support for the heterostructure and superlattice of manganites and superconductors.