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American Institute of Physics, Journal of Applied Physics, 12(101), p. 123521

DOI: 10.1063/1.2749335

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Fundamental band edge absorption in nominally undoped and doped 4H-SiC

Journal article published in 2007 by P. Grivickas, V. Grivickas, J. Linnros ORCID, A. Galeckas
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Fundamental band edge absorption is investigated in nominally undoped (n<1014cm−3) and heavily doped (n∼8×1018cm−3) 4H-SiC by a spectroscopy technique based on spatially and time-resolved free-carrier absorption. The spectra are extracted over a wide absorption range (0.02–500cm−1) at temperatures from 75to450K. The experimental results are supported by an indirect transition theory with a unique set of dominating momentum-conserving phonons, showing good correlation with earlier findings of differential absorption measurements at 2K. Exciton binding energy of 30±10meV is derived from fitting the data at 75K. The detected polarization anisotropy of absorption with respect to c axis is shown to be consistent with the selection rules for the corresponding phonon branches. An analytical model related to constant degree of involved phonons describes well the obtained energy gap variation with temperature. Finally, doping induced band gap narrowing is characterized above the impurity-Mott transition and compared with theoretical calculations in the random phase approximation. The shape of the fundamental absorption edge at high carrier concentrations is discussed in terms of excitonic enhancement above the Mott transition, as recently detected in Si.