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American Chemical Society, Journal of the American Chemical Society, 16(136), p. 5864-5867, 2014

DOI: 10.1021/ja5014745

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Ring-Opening Polymerization of a Strained [3]Nickelocenophane: A Route to Polynickelocenes, a Class of S = 1 Metallopolymers

Journal article published in 2014 by Sladjana Baljak, Andrew D. Russell, Samantha C. Binding, Mairi F. Haddow ORCID, Dermot O’Hare, Ian Manners ORCID
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

We report the synthesis, reactivity studies, and ring-opening polymerization of a tricarba[3]nickelocenophane. The resulting green polynickelocene (5) possesses a -(CH₂)₃- spacer between the nickelocene units and is shown to be of high molecular weight. SQUID magnetometry measurements indicate that 5 is a macromolecular material with an S = 1 repeat unit. ; 4 page(s)