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American Chemical Society, Inorganic Chemistry, 16(53), p. 8257-8269, 2014

DOI: 10.1021/ic5005177

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Relation between the Catalytic Efficiency of the Synthetic Analogues of Catechol Oxidase with Their Electrochemical Property in the Free State and Substrate-Bound State

Journal article published in 2014 by Prateeti Chakraborty, Jaydeep Adhikary, Bipinbihari Ghosh, Ria Sanyal, Shyamal Kumar Chattopadhyay ORCID, Antonio Bauzá, Antonio Frontera, Ennio Zangrando, Debasis Das
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A library of 15 dicopper complexes as synthetic analogues of catechol oxidase has been synthesized with the aim to determine the relationship between the electrochemical behavior of the dicopper(II) species in the absence as well as in the presence of 3,5-di-tert-butylcatechol (3,5-DTBC) as model substrate and the catalytic activity, kcat, in DMSO medium. The complexes have been characterized by routine physicochemical techniques as well as by X-ray single-crystal structure analysis in some cases. Fifteen “end-off” compartmental ligands have been designed as 1 + 2 Schiff-base condensation product of 2,6-diformyl-4-R-phenol (R = Me, tBu, and Cl) and five different amines, N-(2-aminoethyl)- piperazine, N-(2-aminoethyl)pyrrolidine, N-(2-aminoethyl)- morpholine, N-(3-aminopropyl)morpholine, and N-(2-aminoethyl)piperidine