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Wiley, Angewandte Chemie, 29(126), p. 7699-7703, 2014

DOI: 10.1002/ange.201404753

Wiley, Angewandte Chemie International Edition, 29(53), p. 7569-7573

DOI: 10.1002/anie.201404753

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BH, CH, and BC Bond Activation: The Role of Two Adjacent Agostic Interactions

Journal article published in 2014 by Audrey Cassen, Yann Gloaguen, Laure Vendier ORCID, Carine Duhayon, Amalia Poblador-Bahamonde ORCID, Christophe Raynaud ORCID, Eric Clot, Gilles Alcaraz, Sylviane Sabo-Etienne
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Tuning the nature of the linker in a L∼BHR phosphinoborane compound led to the isolation of a ruthenium complex stabilized by two adjacent, δ-CH and ε-Bsp2H, agostic interactions. Such a unique coordination mode stabilizes a 14-electron "RuH2P2" fragment through connected σ-bonds of different polarity, and affords selective BH, CH, and BC bond activation as illustrated by reactivity studies with H2 and boranes.