Published in
Elsevier, Inorganica Chimica Acta, 6(362), p. 2076-2079
DOI: 10.1016/j.ica.2008.09.009
Links
Tools
Synthesis and characterization of Fe(III)(3-CH3O-qsal)2PF6·nH2O (n=0, 2)
Journal article published in 2009 by
João C. Dias,
Bruno Vieira 
,
Isabel C. Santos,
Laura C. J. Pereira ,
Vasco da Gama
,
Isabel C. Santos,
Laura C. J. Pereira ,
Vasco da Gama
This paper is available in a repository.
Full text: Download
Postprint:
archiving forbidden
Published version:
archiving forbidden
Data provided by 
Abstract
Compounds FeIII(3-CH3O-qsal)2PF6 · nH2O (n = 0, 2) (1, 1 · 2H2O) were synthesized and characterized: the structure of 1 and the magnetic properties of both compounds were determined. Compound 1 · 2H2O presents properties characteristic of high-spin Fe(III), while 1 presents properties of low-spin Fe(III) with an onset of a gradual spin crossover at ca. 300 K.