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Elsevier, Inorganica Chimica Acta, 1(373), p. 32-39, 2011

DOI: 10.1016/j.ica.2011.03.037

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Cobalt, nickel, copper and cadmium coordination polymers containing the bis(1,2,4-triazolyl)methane ligand

Journal article published in 2011 by Fabio Marchetti ORCID, Norberto Masciocchi ORCID, Alessandro Figini Albisetti, Claudio Pettinari ORCID, Riccardo Pettinari ORCID
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This paper is available in a repository.

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Abstract

Co(II), Ni(II), Cu(II) and Cd(II) coordination polymers containing the flexible ditopic bis(1,2,4-triazol-1-yl)methane ligand (Btm) have been prepared by reaction of equimolar quantities of the corresponding cobalt, nickel, copper and cadmium salts in EtOH solution. Structure solution and refinement of polycrystalline materials were performed by powder diffraction technique (XRPD), using conventional laboratory data. The results show that architecturally different coordination polymers were obtained depending on the counter-ion employed. The XRPD results show also that non-covalent interactions are driving forces for the occurrence of different structures.