Dissemin is shutting down on January 1st, 2025

Published in

International Union of Crystallography, Acta Crystallographica Section E: Crystallographic Communications, 4(72), p. 548-551, 2016

DOI: 10.1107/s205698901600428x

Links

Tools

Export citation

Search in Google Scholar

Orientational disorder in the one-dimensional coordination polymercatena-poly[[bis(acetylacetonato-κ2O,O′)cobalt(II)]-μ-1,4-diazabicyclo[2.2.2]octane-κ2N1:N4]

Journal article published in 2016 by Florina Dumitru, Ulli Englert ORCID, Beatrice Braun
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

Full text: Download

Green circle
Preprint: archiving allowed
Upload
Green circle
Postprint: archiving allowed
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

The title compound, [Co(C5H7O2)2(C6H12N2)]n, was obtained as a one-dimensional coordination polymer from bis(acetylacetonato)diaquacobalt(II), [Co(acac)2(OH2)2], and 1,4-diazabicyclo[2.2.2]octane (DABCO), a diamine with good bridging ability and rod-like spacer function. In the chain complex that extends along thecaxis, the CoIIatom is six-coordinated, the O-donor atoms of the chelating acac ligands occupying the equatorial positions and the bridging DABCO ligands being intrans-axial positions. In the crystal structure, the DABCO ligand is conformationally disordered in a 50:50 manner as a result of its location across a crystallographic mirror plane. The metal–metal distance is very close to that in a related compound exhibiting weak antiferromagnetic exchange between the CoIIions, and the title compound can thus be useful for obtaining more information about the contribution of different bridges to the magnetic coupling between paramagnetic ions.