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American Chemical Society, Inorganic Chemistry, 20(50), p. 9924-9926, 2011
DOI: 10.1021/ic201394y
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Near-Infrared Luminescent and Magnetic Cyano-Bridged Coordination Polymers Nd(phen)n(DMF)m[M(CN)8] (M = Mo, W)
Journal article published in 2011 by
Jérôme Long,
Elena Chelebaeva,
Joulia Larionova,
Yannick Guari,
Rute A. S. Ferreira,
Luis D. Carlos 
,
Filipe A. Almeida Paz,
Alexander Trifonov,
Christian Guérin
,
Filipe A. Almeida Paz,
Alexander Trifonov,
Christian Guérin
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Abstract
New cyano-bridged coordination polymers [Nd(phen)(2)(DMF)(2)(H(2)O)Mo(CN)(8)]·2H(2)O (1) and [Nd(phen)(DMF)(5)M(CN)(8)]·xH(2)O [M = Mo (2), W (3); phen = 1,10-phenanthroline] have one-dimensional structures with variable number of phenanthroline ligands. Compounds exhibit photoluminescence in the near-infrared region and ferromagnetic Nd(3+)-M(5+) interactions.