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Elsevier, Inorganica Chimica Acta, 5(360), p. 1661-1668, 2007

DOI: 10.1016/j.ica.2006.09.001

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A structural study of late transition metal diethylenetriamine complexes

Journal article published in 2007 by Peter C. Junk ORCID, Johathan Steed
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The synthesis and X-ray crystal structures of u-fac-[Ni(dien)(2)](NO3)(2), s-fac-[Ni(dien)(2)](tos)(2), fac-fac-[(H2O)(dien)Ni(mu-Cl)(2)(dien)-(H2O)]Cl-2, s-fac-[Ni(dien)(2)][ZnCl4], mer-[Ni(dien)(2)][CdCl4] . H2O, fac-[Ni(dien)(H2O)(3)](tos)(2) . (H2O), mer-[Cu(dien)(H2O)]tos)(2), fac-[Zn(dien)(H2O)(2)](tos)(2) (dien = bis(2-aminoethyl)amine = diethylenetriamine; tos = p-toluenesulfonate) are described. The mode of binding of the tridentate amine is examined in detail. Crown Copyright (c) 2006 Published by Elsevier B.V. All rights reserved.