Published in
Sociedade Brasileira de Química, SBQ, Journal of the Brazilian Chemical Society, 2016
DOI: 10.5935/0103-5053.20160072
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Tunable Photochemical/Redox Properties of (Phenylthio)ncorannulenes: Application to a Photovoltaic Device
Journal article published in 2016 by
Steinauer,Angela,
Cotta,Robert W.,
Angela Steinauer,
Anna M. Butterfield,
Butterfield,Anna M.,
Anthony Linden,
Linden,Anthony,
Molina-Ontario,Agustin 
,
David C. Buck,
Buck,David C.,
Robert W. Cotta,
Luis Echegoyen,
Echegoyen,Luis,
Kim K. Baldridge,
Baldridge,Kim K.
and other authors.
,
David C. Buck,
Buck,David C.,
Robert W. Cotta,
Luis Echegoyen,
Echegoyen,Luis,
Kim K. Baldridge,
Baldridge,Kim K.
and other authors.
This paper is made freely available by the publisher.
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Abstract
The additive substituent effect of phenylmercapto derivatives of corannulene are investigated by spectroscopic, electrochemical, and computational techniques. The per-substituted phenylmercaptocorannulene is incorporated as a replacement for [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) in a photovoltaic device.