Novel Azine Reactivity: Facile NN Bond Cleavage, CH Activation, and NN Coupling Mediated by RhI
Journal article published in 2003 by
Revital Cohen,
Boris Rybtchinski,
Mark Gandelman,
Linda J. W. Shimon 
,
Jan M. L. Martin,
David Milstein
,
Jan M. L. Martin,
David Milstein
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Abstract
An unprecedented reaction: Dinitrogen pincer Rh complexes react with azines in a moderately catalytic fashion by "nonsymmetrical" N-N bond cleavage to the corresponding nitriles and imines (see scheme).