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Wiley, Angewandte Chemie International Edition, 17(42), p. 1949-1952, 2003

DOI: 10.1002/anie.200250571

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Novel Azine Reactivity: Facile NN Bond Cleavage, CH Activation, and NN Coupling Mediated by RhI

Journal article published in 2003 by Revital Cohen, Boris Rybtchinski, Mark Gandelman, Linda J. W. Shimon ORCID, Jan M. L. Martin, David Milstein
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This paper is available in a repository.

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Abstract

An unprecedented reaction: Dinitrogen pincer Rh complexes react with azines in a moderately catalytic fashion by "nonsymmetrical" N-N bond cleavage to the corresponding nitriles and imines (see scheme).