The present contribution is aimed at investigating the microstructure evolution of commercially pure silver under severe plastic deformation conditions. ECAP billets have been produced by using a die with channels intersecting at 90° and straining the samples at room temperature. The evolution of the microstructure as a function of imparted strain was evaluated by scanning electron microscopy as well as X-ray diffractometry. Furthermore, tensile properties were measured from ECAP billets in order to evaluate the strengthening and work hardening behaviour of silver as a function of structure evolution. Comparison in terms of grain structure and corresponding properties are also drawn by considering published data about Al-Mg-Si alloy samples ECAP-processed by identical routes and parameters.