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IOP Publishing, Journal of Physics: Conference Series, (325), p. 012009, 2011

DOI: 10.1088/1742-6596/325/1/012009

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Spin delocalization in the molecular manganese tetra-helicate cluster: [Mn3L4](ClO4)2(H2O)2

Journal article published in 2011 by C. Rodríguez Bianco, J. Sánchez Costa, J. A. Rodríguez Velamazán, J. Campo ORCID, B. Gillon, J. Sánchez Costa, P. Gamez, J. Luzón
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The magnetic properties of the compound [Mn3L4](C1O4)2(H2O)2 revealed that it is a rare trinuclear MnII compound showing ferromagnetic interactions and a possible anisotropic behaviour. Here we report preliminary magnetic susceptibility measurements and spin density determinations at the Mn and O atoms to elucidate the magnetic interaction model and the possible anomalous anisotropic magnetic behaviour reported previously for this compound, that it is confirmed to be inexistent.