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Wiley, Advanced Functional Materials, 8(26), p. 1278-1285, 2016

DOI: 10.1002/adfm.201504190

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Enhancing the Optoelectronic Performance of Perovskite Solar Cells via a Textured CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Morphology

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Perovskite-based solar cells are generally assembled as planar structures comprising a flat organoammonium metal halide perovskite layer, or mesoscopic structures employing a mesoporous metal-oxide scaffold into which the perovskite material is infiltrated. To present, little attention has been directed toward the texturing of the perovskite material itself. Herein, a textured CH3NH3PbI3 morphology formed through a thin mesoporous TiO2 seeding layer and a gas-assisted crystallization method is reported. The textured morphology comprises a multitiered nanostructure, which allows for significant improvements in the light harvesting and charge extraction performance of the solar cells. Due to these improvements, average short-circuit current densities for a batch of 28 devices are in excess of 22 mA cm−2, and the maximum recorded power conversion efficiency is 16.3%. The performance gains concomitant with this textured CH3NH3PbI3 morphology provide further insights into how control of the perovskite microstructure can be used to enhance the cell performance.