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American Chemical Society, Inorganic Chemistry, 1(54), p. 200-204, 2014

DOI: 10.1021/ic502116k

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A Three-Dimensional Microporous Metal–Metalloporphyrin Framework

Journal article published in 2014 by Zhiyong Guo, Dan Yan, Hailong Wang, Daniel Tesfagaber, Xinle Li ORCID, Yusheng Chen, Wenyu Huang ORCID, Banglin Chen
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)(2)(H2O)(4)]}center dot(DEF)(20)center dot(CH3OH)(18)center dot(H2O)(12) (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 angstrom. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.