Published in

European Geosciences Union, Atmospheric Chemistry and Physics, 4(4), p. 1071-1083, 2004

DOI: 10.5194/acp-4-1071-2004

European Geosciences Union, Atmospheric Chemistry and Physics Discussions, 6(3), p. 6147-6178

DOI: 10.5194/acpd-3-6147-2003

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Modelling the formation of organic particles in the atmosphere

Journal article published in 2003 by T. Anttila, Vm-M. Kerminen, M. Kulmala ORCID, A. Laaksonen ORCID, Cd D. O’Dowd
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Abstract. Particle formation resulting from activation of inorganic stable clusters by a supersaturated organic vapour was investigated using a numerical model. The applied aerosol dynamic model included a detailed description of the activation process along with a treatment of the appropriate aerosol and gas-phase processes. The obtained results suggest that both gaseous sulphuric acid and organic vapours contribute to organic particle formation in continental background areas. The initial growth of freshly-nucleated clusters is driven mainly by condensation of gaseous sulphuric acid and by a lesser extent self-coagulation. After the clusters have reached sizes of around 2 nm in diameter, low-volatile organic vapours start to condense spontaneously into the clusters, thereby accelerating their growth to detectable sizes. A shortage of gaseous sulphuric acid or organic vapours limit, or suppress altogether, the particle formation, since freshly-nucleated clusters are rapidly coagulated away by pre-existing particles. The obtained modelling results were applied to explaining the observed seasonal cycle in the number of aerosol formation events in a continental forest site.