The Pic 2005 field campaign took place from 13 June to 7 July 2005 close to the high-altitude permanent atmospheric observatory Pic-du-Midi (PDM), situated at 2875 m asl in the French Pyrenees. The experimental set-up combined in situ ground-based observations at PDM with ozone lidar measurements at two lower sites in close vicinity (600 m asl/28 km away, and 2380 m asl/500 m away). Such an experimental configuration is appropriate to address the question of the vertical layering of the chemical atmosphere in a mountain area and above the plain nearby, and how this influences measurements conducted on a mountain summit under the influence of horizontal transport at regional scale, and vertical transport at local scale. Forecast tools made it possible to plan and carry out 6 one-day Intensive Observation Periods (IOPs), mostly in anticyclonic conditions favoring local thermally induced circulations, with and without local pollution in the lower troposphere. It was thus possible to document i) ozone diurnal variations at PDM; ii) correlation between ozone measurements at PDM and their counterparts at the same altitude in the free troposphere; iii) ozone variability in the vicinity of PDM. The field campaign provided direct experimental evidence that at daytime in the encountered conditions (mostly anticyclonic), PDM failed in a large extent to be representative of the troposphere above the surrounding flat areas at similar altitude. First, ozone daily averages at PDM were found lower than their free-tropospheric counterpart. Thermally induced circulations and convection pumping clean air from the rural boundary layer can account qualitatively for ozone depletion observed at PDM during daytime. However the surface measurements do not support the hypothesis of direct lifting of near-surface air masses up to PDM. Thus, mixing with free-tropospheric air, photochemistry and surface deposition in the valleys appear to be needed ingredients to account quantitatively for the observed variations (in proportions that further studies should determine). Second, ozone variability was found to be much lower at PDM than in the free troposphere--again an indication of atmospheric mixing. In particular at daytime, the PDM observatory did not allow for detection of ozone-rich layers simultaneously visible above the plain. Beyond these first results, the data set presented here paves way to detailed studies of the IOPs.