Published in

Elsevier, Surface Science, 1-3(557), p. 41-56, 2004

DOI: 10.1016/j.susc.2004.03.016

Links

Tools

Export citation

Search in Google Scholar

Electrodeposition of Co and Ni/Au(111) ultrathin layers. Part I: nucleation and growth mechanisms from in situ STM

Journal article published in 2004 by P. Allongue, L. Cagnon, C. Gomes, A. Gündel ORCID, V. Costa
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Orange circle
Postprint: archiving restricted
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

The growth mechanisms of Co and Ni/Au(1 1 1) ultrathin layers electrodeposited from dilute sulfate solutions are investigated using in situ STM and electrochemical measurements. Bulk cobalt deposition occurs for potentials 0.25 V negative of the Nernst potential ECo0 of the reaction Co 2+ + 2e - → Co, while bulk nickel may be deposited very close to ENi0. Closer to the Nernst potential slow nucleation is driven by place exchange for both metals. Subsequent growth leads to ML-thick cobalt nanostructures confined onto hcp regions of reconstructed Au(1 1 1) surface, which only cover a small faction of the gold surface, and to a progressive needle growth of nickel until full surface coverage. At greater overpotentials both Co and Ni films grow epitaxially on Au(1 1 1) in a layer-by-layer fashion under appropriate conditions of polarization. The main difference concerns the first Co layer which is strained (4.4%) and biatomic whereas nickel growth starts with a relaxed monolayer. The mechanisms of deposition are discussed from a detailed analysis of STM images, atomic models of the interface are presented and a strain relief mechanism is discussed in light of dissolution experiments.