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EPL Association, European Physical Society Letters, 6(108), p. 67012

DOI: 10.1209/0295-5075/108/67012

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Giant electronic polarization induced by a helical spin order in SrMn 7 O 12 : First-principles calculations

Journal article published in 2014 by H. M. Liu, Shuai Dong, Z. Z. Du, P. Chu, J.-M. Liu
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Through first-principles density functional calculations, the magnetic ground state and electronic structure of mixed-valent manganite SrMn7O12 in the rhombohedral symmetry are investigated in detail. Our calculations show clearly that the possible magnetic ground state accommodates a particular helical spin order responsible for the insulating state in SrMn7O12. The giant ferroelectric polarization is revealed, which is almost purely from the electronic contribution rather than the ionic displacements and is closely related to the magnetism. The influence of the on-site Coulomb interaction and spin-orbit coupling on the electronic structure and multiferroicity is also discussed. The present results suggest that SrMn7O12 is a promising multiferroic candidate with desirable properties. editor's choice Copyright (C) EPLA, 2014