The distributions of polycyclic aromatic hydrocarbons (PAHs) and molecular tracer organic compounds for biomass combustion, traffic emissions, soil dust, and secondary aerosol processing have been studied in three fractions of ambient air particulate matter (PM10, 2.5, and 1) collected in the vicinity of a cement plant. PAH concentrations were used to estimate the carcinogenic risks in humans. Combustion related compounds, including PAHs, and those from secondary aerosol processing, predominated in the finest (PM<1) fraction, while saccharides related to organic soil dust predominated in the coarse fraction (2.5<PM<10). The molecular markers of biomass combustion were found in high concentrations, indicating the influence of biomass burning on PM. Most predominant PAHs were five and six rings species, related to a PAH profile characteristic of urban-industrial environments. The concentrations of benzo[a]pyrene varied between 0.2 and 1.0ng/m(3), which is close but lower than the annual limit value of 1ng/m(3) established by law. Exposure and inhalation carcinogenic risks from total PAHs were below the EPA threshold of acceptable risk (1·10(-6)).