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World Scientific Publishing, Surface Review and Letters, 02(09), p. 1007-1015

DOI: 10.1142/s0218625x02001872

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Electron correlation effects in half-metallic transition metal oxides

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Spin-resolved photoemission and absorption studies of Fe 3 O 4 and CrO 2 epitaxial thin films have been reviewed to address the relationship between the electron correlation effects and the half-metallic properties of these two materials. Spin-resolved photoemission results suggest that Fe 3 O 4 should be considered as a strongly correlated system, and that Fe 3 O 4 is not a half-metal. Spin-resolved O 1s X-ray absorption measurements on ferromagnetic CrO 2 reveal that the spin polarization of the unoccupied states closest to the Fermi level approaches 100%, confirming the half-metallic ferromagnetic nature of the material. The spin polarization of the main line of the unoccupied states, on the other hand, is found to be only 50%, indicating a very atomic-like behavior of the Cr 3d2 ions.