Au/TiO2 catalysts were synthesized by three different methods, with different gold loadings, and tested for the low temperature water–gas shift (WGS) reaction. Gold was loaded by a Double Impregnation Method (DIM), Deposition–Precipitation (DP) and Liquid Phase Reductive Deposition (LPRD). For each procedure, catalysts were synthesized with three different loadings of gold, up to ca. 2.5 wt.%, identified as 1, 2 or 3 for low, intermediate or high amounts of nanosized gold, respectively. The prepared materials were characterized by High-Resolution Transmission Electron Microscopy (HR-TEM), X-Ray Diffraction (XRD), X-Ray Photoelectron Spectroscopy (XPS), Temperature Programmed Reduction (TPR) and Absorption Atomic Spectroscopy (AAS).